Moore consolidates the break against Zvonareva and is 2-0 up in the final set.
Brother Murray, meanwhile, is through to the second round of the men's doubles with Peer after the pair beat Evans and Ward 6-2 6-4 6-4.
Great start for Murray, and a great start for Moore as she also has a break against Zvonareva.
And Murray gets an immediate break to take a 1-0 lead after Rola's double-handed backhand went wide.
Murray with two break points...
Rola to get the ball rolling as he is serving first against Murray.
Venus Williams up a break in the second set as she lead Kurumi Nara 3-1.
Murray receives a nice welcome on Court No.1, who are no doubt delighted to see the defending champion as many would've been thinking he would be playing on Centre Court.
It's nearly time for Andy Murray as Court No.1 is filling up nicely for the defending champion's match against Blaz Rola.
While Venus, who arrived late for the start of the match, went off court at the end of the first set, her opponent Nara has been receiving treatment for her back and is now having a medical timeout.
And Li will serve for the match after taking a 5-2 lead.
Meanwhile, Li has consolidated the break of serve to lead 4-2 in the second set. She's also a set up on Meusburger as well.
Venus with two set points...
Venus from 4-1 down is now 5-4 up in the tiebreak.
Nara, meanwhile, is 4-1 up in the tiebreak against Venus.
Li up a break for the second time in the set and leads Meusburger 3-2.
In the doubles, Evans and Ward have lost the second set 6-4 to Murray and Peers. Turning out to be a miserable Wimbledon so far for them.
Venus holds for 6-6 and the first set with Nara goes to a tiebreak.
Li trails 2-1 to Meusburger.
Nara 6-5 up on Venus Williams. Venus serving to stay in the opening set.
Meusburger breaks back against Li in the second set and it's now 1-1.
Nara breaks back to make it 5-5 against Venus
Li already up a break in the second set.
Nara stops the rot and trails Venus 5-4.
Five games in a row for Venus now as she leads Nara 5-3.
And Li takes the first set 6-2 against Meusburger. Easy for the No.2 seed so far.
Li 5-2 up and serving for the first set.
Venus takes four games in a row to lead 4-3
Li up a break in the first set as she leads 4-2 against Meusburger.
Venus comes from 3-0 down to make it 3-3.